alpha-Tocotrienol

S-Adenosyl-L-methionine + gamma-Tocotrienol ⇄ S-Adenosyl-L-homocysteine + alpha-Tocotrienol (2.1.1.95)
S-Adenosyl-L-methionine: amet_c

gamma-Tocotrienol

6-Geranylgeranyl-2,3-dimethylbenzene-1,4-diol ⇄ gamma-Tocotrienol (5.5.1.24)

Reversibility:

-25.65±2.38

6-Geranylgeranyl-2,3-dimethylbenzene-1,4-diol

S-Adenosyl-L-methionine + 6-Geranylgeranyl-2-methylbenzene-1,4-diol ⇄ S-Adenosyl-L-homocysteine + 6-Geranylgeranyl-2,3-dimethylbenzene-1,4-diol (2.1.1.295)
S-Adenosyl-L-methionine: amet_c

Reversibility:

?

6-Geranylgeranyl-2-methylbenzene-1,4-diol

Geranylgeranyl diphosphate + Homogentisate ⇄ Diphosphate + 6-Geranylgeranyl-2-methylbenzene-1,4-diol + CO₂ (2.5.1.116)

Reversibility:

-18.74±0.67

Geranylgeranyl diphosphate

trans,trans-Farnesyl diphosphate + Isopentenyl diphosphate ⇄ Diphosphate + Geranylgeranyl diphosphate (2.5.1.29)
trans,trans-Farnesyl diphosphate: frdp_c, Isopentenyl diphosphate: ipdp_c

Reversibility:

-16.40±0.59

Homogentisate

4-Maleylacetoacetate ⇄ Homogentisate + O₂ (1.13.11.5)

Reversibility:

66.40±1.53

4-Maleylacetoacetate

4-Fumarylacetoacetate ⇄ 4-Maleylacetoacetate (5.2.1.2)

Reversibility:

0.00±0.00

4-Fumarylacetoacetate

Acetoacetate + Fumarate ⇄ 4-Fumarylacetoacetate + H₂O (3.7.1.2)
Acetoacetate: acac_c, Fumarate: fum_c

Reversibility:

25.11±1.03