Rebeccamycin

4'-O-Demethylrebeccamycin + S-Adenosyl-L-methionine ⇄ Rebeccamycin + S-Adenosyl-L-homocysteine (2.1.1.164)
S-Adenosyl-L-methionine: amet_c

4'-O-Demethylrebeccamycin

Dichloroarcyriaflavin A + beta-D-Glucose ⇄ 4'-O-Demethylrebeccamycin + H₂O (4.3.3.5)

Reversibility:

7.49±0.50

Dichloroarcyriaflavin A

3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 4 O₂ + 4 NADH + 4 H⁺ ⇄ Dichloroarcyriaflavin A + 2 CO₂ + 6 H₂O + 4 NAD⁺ (1.13.12.17)
O₂: o2_c, NADH: nadh_c, H⁺: h_c

Reversibility:

-92.73±1.22

3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate

4 2-Imino-3-(7-chloroindol-3-yl)propanoate + O₂ ⇄ 2 3,4-Bis(7-chloroindol-3-yl)pyrrole-2,5-dicarboxylate + 2 Ammonia + 2 H₂O (1.21.98.2)
O₂: o2_c

Reversibility:

?

2-Imino-3-(7-chloroindol-3-yl)propanoate

7-Chloro-L-tryptophan + O₂ ⇄ 2-Imino-3-(7-chloroindol-3-yl)propanoate + Hydrogen peroxide (1.4.3.23)
O₂: o2_c

Reversibility:

?

7-Chloro-L-tryptophan

L-Tryptophan + FADH2 + Cl- + O₂ + H⁺ ⇄ 7-Chloro-L-tryptophan + FAD + 2 H₂O (1.14.19.9)
L-Tryptophan: trp__L_c, FADH2: fadh2_c, Cl-: cl_c, O₂: o2_c, H⁺: h_c

Reversibility:

?

beta-D-Glucose

D-Glucono-1,5-lactone + Hydrogen peroxide ⇄ beta-D-Glucose + O₂ (1.1.3.4)
Hydrogen peroxide: h2o2_c

Reversibility:

27.94±0.90

D-Glucono-1,5-lactone

D-Glucose + NAD⁺ ⇄ D-Glucono-1,5-lactone + NADH + H⁺ (1.1.1.118)
D-Glucose: glc__D_c, NAD⁺: nad_c

Reversibility:

-1.50±0.23