Ferulate

S-Adenosyl-L-methionine + Caffeate ⇄ S-Adenosyl-L-homocysteine + Ferulate (2.1.1.68)
S-Adenosyl-L-methionine: amet_c

Caffeate

3,4-Dihydroxyphenylpropanoate + Caffeoyl-CoA ⇄ Dihydrocaffeoyl-CoA + Caffeate (2.8.3.23)

Reversibility:

0.02±0.00

3,4-Dihydroxyphenylpropanoate

3,4-Dihydroxy-L-phenylalanine + NADH + H⁺ ⇄ 3,4-Dihydroxyphenylpropanoate + NAD⁺ + Ammonia (4.3.1.22)
NADH: nadh_c, H⁺: h_c

Reversibility:

-10.31±0.29

3,4-Dihydroxy-L-phenylalanine

L-Tyrosine + Hydrogen peroxide ⇄ 3,4-Dihydroxy-L-phenylalanine + H₂O (1.11.2.6)
L-Tyrosine: tyr__L_c, Hydrogen peroxide: h2o2_c

Reversibility:

-92.17±1.62

Caffeoyl-CoA

S-Adenosyl-L-homocysteine + Feruloyl-CoA ⇄ S-Adenosyl-L-methionine + Caffeoyl-CoA (2.1.1.104)
S-Adenosyl-L-homocysteine: ahcys_c

Reversibility:

?

Feruloyl-CoA

4-Hydroxy-3-methoxy-benzaldehyde + Acetyl-CoA ⇄ Feruloyl-CoA + H₂O (4.1.2.61)
Acetyl-CoA: accoa_c

Reversibility:

4.96±0.48

4-Hydroxy-3-methoxy-benzaldehyde

Vanillate + NADH + H⁺ ⇄ 4-Hydroxy-3-methoxy-benzaldehyde + NAD⁺ + H₂O (1.2.1.67)
NADH: nadh_c, H⁺: h_c

Reversibility:

8.56±0.22

Vanillate

3,4-Dihydroxybenzoate + NAD⁺ + H₂O + Formaldehyde ⇄ Vanillate + O₂ + NADH + H⁺ (1.14.13.82)
NAD⁺: nad_c, H₂O: h2o_c, Formaldehyde: fald_c

Reversibility:

50.17±0.70

3,4-Dihydroxybenzoate

4-Hydroxybenzoate + O₂ + NADPH + H⁺ ⇄ 3,4-Dihydroxybenzoate + NADP⁺ + H₂O (1.14.13.2)
4-Hydroxybenzoate: 4hbz_c, O₂: o2_c, NADPH: nadph_c, H⁺: h_c

Reversibility:

-68.23±0.61

Feruloyl-CoA

4-Hydroxy-3-methoxyphenyl-beta-hydroxypropanoyl-CoA ⇄ Feruloyl-CoA + H₂O (4.1.2.61)

Reversibility:

-0.18±0.60

4-Hydroxy-3-methoxyphenyl-beta-hydroxypropanoyl-CoA

4-Hydroxy-3-methoxy-benzaldehyde + Acetyl-CoA ⇄ 4-Hydroxy-3-methoxyphenyl-beta-hydroxypropanoyl-CoA (4.1.2.61)
Acetyl-CoA: accoa_c

Reversibility:

5.08±0.30

4-Hydroxy-3-methoxy-benzaldehyde

Vanillate + NADH + H⁺ ⇄ 4-Hydroxy-3-methoxy-benzaldehyde + NAD⁺ + H₂O (1.2.1.67)
NADH: nadh_c, H⁺: h_c

Reversibility:

8.56±0.22

Vanillate

3,4-Dihydroxybenzoate + NAD⁺ + H₂O + Formaldehyde ⇄ Vanillate + O₂ + NADH + H⁺ (1.14.13.82)
NAD⁺: nad_c, H₂O: h2o_c, Formaldehyde: fald_c

Reversibility:

50.17±0.70

3,4-Dihydroxybenzoate

4-Hydroxybenzoate + O₂ + NADPH + H⁺ ⇄ 3,4-Dihydroxybenzoate + NADP⁺ + H₂O (1.14.13.2)
4-Hydroxybenzoate: 4hbz_c, O₂: o2_c, NADPH: nadph_c, H⁺: h_c

Reversibility:

-68.23±0.61